Researchers: New fertilizer technology to benefit biogas industry

By Aalto University | January 19, 2017

Researchers of Aalto University have developed a new, energy-efficient method for capturing nitrogen and phosphorus from different liquid waste fractions. In laboratory studies, with the help of the method, it is possible to separate 99 percent of the nitrogen and 90-99% percentof phosphorus in wastewater and produce granular ammonium sulphate (NH4)2SO4 and phosphorus precipitate suitable for fertilizers.

“There are many different methods for removing nitrogen and phosphorus from wastewater, but none of them meets the need of capturing their nutrients. It is estimated that the industrial production of nitrogen used for fertilizers is responsible for approximately 2 percent of the entire world's energy consumption. By capture of nutrients from communities' wastewater it is possible to supplement 6 percent of the industrially produced ammoniacal nitrogen and about one-tenth of phosphorus used for fertilizers,” says Riku Vahala, professor of water and wastewater engineering at Aalto University.

The construction of pilot equipment at the laboratory of Water and Environmental Technology at Aalto University will begin in spring 2017. The main objective of the project is to develop an economically profitable process and operation chain for the recycling of nutrients of liquid waste fractions. Simultaneously, entrepreneurs in the field will be encouraged to migrate towards efficient wastewater treatment. Increased efficiency in nutrient capture will reduce nutrient load in the Baltic Sea, reduce the costs of wastewater treatment and promote recycling of nutrients.

“The specific beneficiaries in the project include wastewater treatment plants, sludge producers and handlers, biogas plants and the end users of fertilizers, who will get a sustainable fertilizer product for their use,” says Surendra Pradhan, DSc (Tech).

The capture method is based on the use of calcium hydroxide Ca(OH)2 to convert ammoniacal nitrogen NH4+ into ammoniacal gas NH3, which are separated through a semi-permeable membrane. Following this, the ammonium is dissolved into sulphuric acid to produce ammonium sulphate. In the process, the phosphorus is precipitated with the help of calcium salt.

“A patent application for the method is currently under way, and the aim of the project is to find company partners who could make use of the patent in the best possible manner, create products with its help and market the new process. If successful, the new process will also create a competitive export product,” Anna Mikola, DSc (Tech), points out.

The method also has significant positive impacts on the environment.

“Nutrient emissions to waterways will decrease, and the energy savings and reduced use of chemicals in the production of fertilizers will lower the amount of greenhouse gases,” Professor Vahala reminds us.